The performance of Abraham Darby I’s coke furnace revisited, part 1: temperature of operation
Abstract
Abraham Darby I’s coke-fired furnace produced a higher-silicon iron than prior charcoal ones, which was critical for the casting of thin pots in sand. This silicon content has hitherto been attributed to an enforced higher temperature of operation with coke. This paper sets out to show that there were other reasons why coke iron had a higher silicon content than charcoal iron, and that the temperature in his hearth was probably no higher than that in a charcoal furnace. The causes of high silicon content in coke iron were the higher density of coke, leading to a longer dwell time, and the now-appreciated effect of reactive silica in the coke, not present in charcoal. The paper suggests that the breakthrough by Abraham Darby II that led to coke iron being fit for the forges was the removal of sulphur by using higher temperatures in bigger furnaces.
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